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Enhanced Hypsochromic Shifts, Quantum Yield, and π–π Interactions in a <i>meso</i>,β-Heteroaryl-Fused BODIPY

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NIAID Data Ecosystem2026-03-10 收录
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We report the synthesis and investigation of an unprecedented 8-heteroaryl-fused BODIPY 4. This compound exhibits enhanced π–π stacking in the solid state, unusually large blue-shifts in the absorbance and emission spectra, and higher fluorescence quantum yield than its unfused precursor; DFT calculations suggest a small energy gap for 4 and strong electronic communication between the 8-OPh and the BODIPY core.

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2017-03-10
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