Biomimetic Synthesis of <i>ent</i>-(−)-Azonazine and Stereochemical Reassignment of Natural Product
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The first total synthesis of ent-(−)-azonazine has been accomplished using a hypervalent iodine-mediated biomimetic oxidative cyclization to construct the highly strained core. Based on the results from the completed synthesis, both the relative and absolute configurations of natural (+)-azonazine were revised.
创建时间：
2016-02-18
