Desymmetrizing Hydroformylation with the Aid of a Planar Chiral Catalyst-Directing Group
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Desymmetrizing hydroformylation of bisalkenyl- and bisallylcarbinols could be achieved employing a chiral substrate-bound catalyst-directing group (o-DPPF) with excellent levels of diastereotopic alkene face and diastereotopic alkene group discrimination to give bifunctionalized chiral aldehydes in enantiomerically pure form.
创建时间：
2004-08-25
