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Out-of-equilibrium phase separation in Ti3O5 single crystals

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ESRF Portal2028-01-01 更新2026-04-23 收录
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https://doi.esrf.fr/10.15151/ESRF-ES-2159193277
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The proposal aims at understanding the phase separation dynamics in a single crystal of Ti3O5 during ultra-fast semiconductor (β) to metal (λ) phase transition. Previous time-resolved X-ray diffraction(XRD) studies on this system were performed on polycrystalline samples. They gave indication of phase separation within a single crystallite, with however no direct evidence. Time-resolved XRD on a single object will give a precise picture and understanding of this domain dynamics, which plays a dominant role in the stability of the photo-induced phase. This result will help to optimise the design of Ti3O5 compounds and other emerging nanomaterials with similar properties, for any technological application exploiting the materials bistability.
提供机构:
UMR CNRS UR1 6251 - Universite Rennes 1, Institut de Physique de Rennes - IPR, Campus de Beaulieu, 35042 Rennes Cedex, France; Universite de Tours, GREMAN, Parc de Grandmont, Tours, 37000 Tours, France; CNRS UMR 6502 - Universite de Nantes, Laboratoire de Chimie des Solides, Institut des Matériaux Jean Rouxel 2 rue de la Houssinière BP 32229, 44322, Nantes, FR; Institut des Materiaux de Nantes, 2 rue de la Houssiniere, 44072 NANTES Cedex 03, France; Lund University, MAX IV Laboratory, Electrongatan 3 P.O. Box 118, 221 00 , Lund, SWEDEN; University of Tsukuba, Tennodai Tsukuba Ibaraki, 305-8577 , Tsukuba, JAPAN; UMR CNRS UR1 6251 - Universite Rennes 1, Institut de Physique de Rennes - IPR, Campus de Beaulieu, 35042 , Rennes, FRANCE; UMR CNRS UR1 6251 - Universite Rennes 1, Institut de Physique de Rennes - IPR, Campus de Beaulieu, 35042 , Rennes, FR
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2028-01-01
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