Synthesis of <i>C</i><sub>5</sub>-Symmetric Functionalized [60]Fullerenes by Copper-Mediated 5-Fold Addition of Reformatsky Reagents
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
A variety of Reformatsky reagents were added five times to [60]fullerene in good yield in the presence of a stoichiometric amount of a copper(I) complex. The penta-addition products C60(CH2CO2R)5H (R = Et, t-Bu, CH2CF3, (CH2CH2O)2Et, and CH2CH2CCSiMe3) can then be converted to the corresponding penta-hapto metal complexes. When the R group is a (−)-menthyl group, the corresponding metal complex comprises an organometallic complex with a coordination sphere consisting of a homochiral C5-symmetric environment.
创建时间：
2016-06-03
