A Dithiolate-Bridged (CN)<sub>2</sub>(CO)Fe−Ni Complex Reproducing the IR Bands of [NiFe] Hydrogenase
收藏NIAID Data Ecosystem2026-03-06 收录
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A dithiolate-bridged dinuclear Fe−Ni complex, which has the desired fac-(CN)2(CO) ligand set at iron, has been synthesized. Its CN/CO bands in the IR spectrum reproduce those of the Ni−A, Ni−B, and Ni−SU states, which indicate that these octahedral FeII centers have similar electronic properties. This result verifies the assignment of a (CN)2(CO)FeII moiety in the active site of [NiFe] hydrogenase.
创建时间：
2016-02-26
