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Cluster model of molecules

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Mendeley Data2024-03-27 更新2024-06-26 收录
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The term "cluster model of molecules" was proposed by de Gennes. De Gennes pointed out that the key to the glass state theory is to find the spin interaction between two adjacent hard-sphere molecules (HSMs). This interaction has now been discovered as the de Gennes n = 0 cluster-interaction boson (CI-boson), which is the unit length vector making up the interface of the 2D clusters at the bottom of the potential well. All CI-boson-derived 2D cluster data are divided into seven sections: the discovery process of CI-boson, the definition of new concepts, symbols and labeling methods, the cluster-peculation transition at the Kauzmann temperature, the largest 2D cluster at the glass transition, the 20-fold symmetry of CI-boson, the 20 CI-boson interaction maps of each HSM, and closed-loop hop path for each HSM in the soft matrix. All of these are the geometric data of the n = 0 2D spin system inherent to disorder system itself.

"分子团簇模型(cluster model of molecules)"这一概念由德热纳(de Gennes)提出。德热纳指出,玻璃态理论的核心在于探明两个相邻硬球分子(hard-sphere molecules, HSMs)之间的自旋相互作用。目前该相互作用已被证实为德热纳n=0团簇相互作用玻色子(cluster-interaction boson, CI-boson),其为构成势阱底部二维团簇界面的单位长度矢量。所有源自CI-玻色子的二维团簇数据被划分为七个部分:CI-玻色子的发现历程、新概念、符号与标记方法的定义、考兹曼温度(Kauzmann temperature)下的团簇逾渗转变、玻璃化转变时的最大二维团簇、CI-玻色子的二十重对称性、每个硬球分子对应的20张CI-玻色子相互作用图谱,以及软基质中每个硬球分子的闭环跳跃路径。上述所有内容均为无序系统自身固有的n=0二维自旋系统的几何数据。

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2024-01-23
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