Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center
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https://figshare.com/articles/dataset/Decarbonylation_of_Acetone_and_Carbonate_at_a_Pincer_Ligated_Ru_Center/3304528
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资源简介：
A Ru center ligated by a pincer bis(o-phosphinoaryl)amine (PNP) ligand in (PNP)RuH(H2) is
sufficiently electron rich to break C−O and C−C bonds,
resulting in the ultimate decarbonylation of hydrocarbonate and acetone, respectively, to give (PNP)RuH(CO).
The decarbonylation of acetone is accompanied by hydrogenolysis of the C−C bonds to produce methane.
创建时间：
2016-05-06
