Stereoselective Synthesis of Baylis−Hillman-Type Adducts via Allenolates Generated by Acyl Migration
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_Baylis_Hillman_Type_Adducts_via_Allenolates_Generated_by_Acyl_Migration/3318856
下载链接
链接失效反馈官方服务：
资源简介：
The rearrangement of the carbamoyl group in allenyl carbamate 1 in the presence of n-BuLi in situ generates the allenolate 3, which is
subsequently intercepted with aromatic aldehydes furnishing (Z)- or (E)-configured Baylis−Hillman-type adducts 4 or 5. The double bond
isomers can be interconverted by a retro aldol-type reaction.
创建时间：
2016-05-06
