Combining Dynamic Heteroleptic Complex Formation with Constitutional Dynamic Synthesis: A Facile Way to M<sub>3</sub>LL′ Cage Assemblies
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The quantitative preparation of heteroleptic copper(I) complexes arising from a combination of 2,9-diarylphenanthrolines and iminopyridines (Schiff bases) is described. This strategy was applied to construct mono- and binuclear complexes but equally a discrete three-dimensional M3LL′ cage. By means of a constitutional dynamic synthesis, the heteroleptic aggregates were equally prepared from four-component mixtures using the copper(I) center as a catalyst for the in situ generation of the iminopyridine ligands.
创建时间：
2009-07-20
