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Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation

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https://figshare.com/articles/dataset/Crossed_Intramolecular_Rauhut_Currier_Type_Reactions_via_Dienamine_Activation/2827564
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资源简介:
The intramolecular Rauhut−Currier reaction creates a carbon−carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework.
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2009-09-17
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