Thermal Dearomative Rearrangement of α-(Prop-2-enyl)-α’-(pyridin-2-yl) Malonates Derivatives towards 4H-Dihydroquinolizines: NMR data (pure compounds)

The thermally induced dearomative rearrangement of α-(aza-heteroaryl)-α’-prop-2-enyl malonates derivatives afforded 4H-dihydroquinolizine derivatives (21 examples, 26-94%). The rearrangement assisted by microwave activation afforded diastereoselectively quinolizidine scaffolds, known for their broad biological activities. These data are the NMR raw data (primary NMR FID files) of all new compounds.