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Difluorodioxophosphate-Based Hollow Hexanuclear Lanthanide(III) Clusters Decorated with Tetrathiafulvalene Ligands

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Figshare2016-02-18 更新2026-04-29 收录
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The galvanostatic reaction of the [4,5-bis­(2-pyridyl-N-oxidemethylthio)]-4′,5′-methyldithiotetrathiafulvalene ligand with lanthanide ions in the presence of hexafluorophosphate (PF6–) anions afforded the highest-nuclearity lanthanide clusters decorated by tetrathiafulvalene-based ligands thanks to the original partial hydrolysis of the PF6– anions in difluorodioxophosphate (PO2F2–) bridging ligands.

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2016-02-18
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