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Reactivity of Decamethylzirconocene Trihydride Anion with Protic Reagents

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https://figshare.com/articles/dataset/Reactivity_of_Decamethylzirconocene_Trihydride_Anion_with_Protic_Reagents/3762222
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资源简介:
The reactions of [(C5Me5)2ZrH3Li]3 (1) with 2,6-diisopropylphenol, aniline, and o-methoxyaniline gave Cp*2ZrH(OC6H3(2,6-i-Pr2)) (2), Cp2*Zr(NHPh)2 (3), and Cp2*Zr(NH(C6H4OMe))2 (4), respectively. In contrast, reaction of 1 with thiophenol afforded [(Cp*2ZrH3)(LiTHF)]2(LiSPh) (5). The implications of these results are considered. Crystallographic data for 3−5 are reported.
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2016-08-26
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