A Neutral Gold(III)–Boron Transmetalation
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https://figshare.com/articles/dataset/A_Neutral_Gold_III_Boron_Transmetalation/2312590
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资源简介:
The
occurrence of direct transmetalation between gold(III) and
boron species during gold-catalyzed cross-coupling reactions has recently
become the subject of intense discussion. In this work, we investigate
the transmetalation reaction between discrete, stable gold(III) complexes
and boron reagents. Interestingly, electron-rich arylboronic acids
remain unreactive under neutral conditions, whereas electron-deficient
species undergo transmetalation in a highly efficient manner.
创建时间:
2016-02-17



