Synthesis of 4-Oxoindeno[1,2-b]pyrroles through Copper-Catalyzed Tandem Reactions of 1-(2-Haloaryl)enones with Isocyanides
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0030-1260171
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资源简介:
Copper-catalyzed tandem reactions of 1-(2-haloaryl)-enones
with isocyanides for the synthesis of 4-oxoindeno[1,2-b]pyrroles are described. Highly
reactive cyclic organocopper intermediates are generated in the
copper-catalyzed [3+2]-cycloaddition reactions
of isocyanides to double or triple bonds. Successful intramolecular
trapping of the organocopper intermediates led to the efficient
formation of 4-oxoindeno[1,2-b]pyrroles.
提供机构:
Georg Thieme Verlag, Stuttgart, New York
创建时间:
2011-11-09



