Activation of Aryl Halides at Gold(I): Practical Synthesis of (P,C) Cyclometalated Gold(III) Complexes
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https://figshare.com/articles/dataset/Activation_of_Aryl_Halides_at_Gold_I_Practical_Synthesis_of_P_C_Cyclometalated_Gold_III_Complexes/2326801
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资源简介：
Taking
advantage of phosphine chelation, direct evidence for oxidative
addition of Csp2–X bonds (X = I, Br)
to a single gold atom is reported. NMR studies and DFT calculations
provide insight into this unprecedented transformation, which gives
straightforward access to stable (P,C) cyclometalated gold(III) complexes.
创建时间：
2014-02-05
