Samarium-Mediated Tandem Reactions of <i>o</i>-Carborane. Synthesis and Molecular Structure of [{η<sup>5</sup>:η<sup>1</sup>:η<sup>6</sup>-Me<sub>2</sub>Si(C<sub>9</sub>H<sub>5</sub>CH<sub>2</sub>CH<sub>2</sub>G)(C<sub>2</sub>B<sub>10</sub>H<sub>10</sub>)Sm}<sub>2</sub>(<i>μ</i>-Cl)][Li(THF)<sub>4</sub>] (G = NMe<sub>2</sub> and OMe)
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数据链接：
https://figshare.com/articles/dataset/Samarium-Mediated_Tandem_Reactions_of_i_o_i_-Carborane_Synthesis_and_Molecular_Structure_of_sup_5_sup_sup_1_sup_sup_6_sup_-Me_sub_2_sub_Si_C_sub_9_sub_H_sub_5_sub_CH_sub_2_sub_CH_sub_2_sub_G_C_sub_2_sub_B_sub_10_sub_H_sub_10_sub_Sm_sub_2_sub_i_i_-Cl_Li_TH/3765597数据链接链接失效反馈
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资源简介：
New metallacarboranes bearing a (nido-RC2B10H10)24- ligand, [{η5:η1:η6-Me2Si(C9H5CH2CH2G)(C2B10H10)Sm}2(μ-Cl)][Li(THF)4] (G = NMe2 (1), OMe (2)), have been prepared and structurally characterized by treatment of SmI2(THF)x with 1 equiv of [Me2Si(C9H5CH2CH2G)(C2B10H10)]Li2(OEt2)2·LiCl in THF via unexpected samarium-mediated tandem reactions.
创建时间：
2016-08-26
