Tandem Nazarov Cyclization−Michael Addition Sequence Catalyzed by an Ir(III) Complex
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https://figshare.com/articles/dataset/Tandem_Nazarov_Cyclization_Michael_Addition_Sequence_Catalyzed_by_an_Ir_III_Complex/3225667
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资源简介：
The first examples of a tandem Nazarov cyclization/Michael addition process are described. The sequence is efficiently catalyzed by Ir[Me(CO)(dppe)(DIB)]2+ and occurs with high diastereoselectivity, creating three contiguous stereocenters. The mechanistic factors controlling the reactivity and diastereoselectivity are discussed.
创建时间：
2016-05-05
