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Novel Stable Silyl, Germyl, and Stannyl Germanium(II) Compounds Containing an Amidinato Ligand

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NIAID Data Ecosystem2026-03-07 收录
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Reactions of the N,N′-chelated chlorogermanium(II) compound [Me3SiNC(Ph)NSiMe3]GeCl with the magnesium reagents Mg[E(SiMe3)3]2 (E = Si, Ge, Sn) gave the new metallyl germylenes [Me3SiNC(Ph)NSiMe3]GeE(SiMe3)3, representing the first isolated silyl- and stannylgermylenes. These compounds have been fully characterized by multinuclear NMR spectroscopy and their structures determined by X-ray diffraction analysis.

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2011-04-25
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