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Regio- and Chemoselective Diboration of Allenes with Unsymmetrical Diboron: Formation of Vinyl and Allyl Boronic Acid Derivatives

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Regio_and_Chemoselective_Diboration_of_Allenes_with_Unsymmetrical_Diboron_Formation_of_Vinyl_and_Allyl_Boronic_Acid_Derivatives/2180428
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资源简介:
A platinum-catalyzed terminal diboration of 1,1-disubstituted allenes using a differentially protected diboron is described. Diboration occurs in a regio- and chemoselective fashion to furnish vinyl and allyl boronates in good to excellent yield and selectivity. Transformation of the bis-boronyl products to other functional groups as well as in chemoselective cross-coupling is demonstrated.
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2016-02-13
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