Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe–M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination
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下载链接：
https://figshare.com/articles/dataset/Ferrocene-bis_phosphinimine_Nickel_II_and_Palladium_II_Alkyl_Complexes_Influence_of_the_Fe_M_M_Ni_and_Pd_Interaction_on_Redox_Activity_and_Olefin_Coordination/5580169
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资源简介：
The
synthesis of several novel nickel(II) and palladium(II) ferrocene-bis(phosphinimine)
alkyl complexes containing iron–nickel and iron–palladium
interactions is reported. The redox behavior of all complexes was
evaluated electrochemically and chemically; in addition, reactions
with weak nucleophiles, such as acetonitrile and olefins, were also
investigated. DFT calculations were performed to understand the electronic
structure of the alkyl metal complexes.
创建时间：
2017-11-08
