[Ni(HF<sub>2</sub>)(3-Clpy)<sub>4</sub>]BF<sub>4</sub> (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F<sup>–</sup> Bridges in a One-Dimensional Polymeric Chain
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[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2– ligands. In spite of significant distortion of the HF2– bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with JFHF = 4.86 K.
创建时间：
2012-07-16
