Selective Oxidations in the Synthesis of Complex Natural <i>ent</i>-Kauranes and <i>ent</i>-Beyeranes
收藏NIAID Data Ecosystem2026-03-13 收录
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Syntheses of two natural products derived from the ent-kaurene kaurenoic acid are described for the first time using regio- and diastereoselective oxidations. Palladium- and manganese-mediated oxidations were used to accomplish the syntheses of two ent-beyerane metabolites. The use of the White–Gormisky–Zhao catalyst Mn(CF3-PDP) enabled the first application of a nondirected metal-catalyzed oxidation in an unactivated C–H bond in a total synthesis.
创建时间：
2022-07-21
