Nickel-Catalyzed Cross Couplings of Benzylic Ammonium Salts and Boronic Acids: Stereospecific Formation of Diarylethanes via C–N Bond Activation
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https://figshare.com/articles/dataset/Nickel_Catalyzed_Cross_Couplings_of_Benzylic_Ammonium_Salts_and_Boronic_Acids_Stereospecific_Formation_of_Diarylethanes_via_C_N_Bond_Activation/2453779
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资源简介：
We have developed a nickel-catalyzed cross coupling of
benzylic
ammonium triflates with aryl boronic acids to afford diarylmethanes
and diarylethanes. This reaction proceeds under mild reaction conditions
and with exceptional functional group tolerance. Further, it transforms
branched benzylic ammonium salts to diarylethanes with excellent chirality
transfer, offering a new strategy for the synthesis of highly enantioenriched
diarylethanes from readily available chiral benzylic amines.
创建时间：
2016-02-20
