Modular Enantioselective Synthesis of cis-Cyclopropanes through Self-Sensitized Stereoselective Photo-Decarboxylation with Benzothiazolines

NIAID Data Ecosystem2026-03-13 收录

手性环丙烷化

光催化脱羧反应

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https://zenodo.org/record/5575492 数据链接链接失效反馈

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资源简介：

Raw data for the characterization of the compounds in the research paper with the same name.

创建时间：

2021-10-18

Desymmetrization of Cyclopropenes via the Potassium-Templated Diastereoselective 7- exo - trig Cycloaddition of Tethered Amino Alcohols toward Enantiopure Cyclopropane-Fused Oxazepanones with Antimycobacterial Activity

手性环丙烷化

分枝杆菌药物筛选

A strain-release-driven, cation-templated intramolecular nucleophilic addition of tethered alkoxides to prochiral cyclopropenes is described. Employment of chiral β- and γ-amino alkoxides allowed for

NIAID Data Ecosystem70

Oxazaborolidinium Ion-Catalyzed Cyclopropanation of α-Substituted Acroleins: Enantioselective Synthesis of Cyclopropanes Bearing Two Chiral Quaternary Centers

手性环丙烷化

不对称催化

A catalytic synthetic route to highly functionalized chiral cyclopropane derivatives was developed by Michael-initiated cyclopropanation of α-substituted acroleins with aryl- and alkyl diazoacetates.

NIAID Data Ecosystem60

Diastereoselective Michael Initiated Ring Closure on Vinyl Sulfone-Modified Carbohydrates: A Stereospecific and General Route to α-Substituted Cyclopropanes

有机合成方法

手性环丙烷化

Suitably designed vinyl sulfone-modified furanosides act as substrates for Michael initiated ring closure reactions yielding cyclopropanated carbohydrates. The strategy is general in nature and gives

NIAID Data Ecosystem30

One-Pot Catalytic Enantio- and Diastereoselective Syntheses of anti -, syn - cis -Disubstituted, and syn -Vinyl Cyclopropyl Alcohols

手性环丙烷化

不对称催化

Highly enantio- and diastereoselective methods for the synthesis of a variety of cyclopropyl alcohols are reported. These methods represent the first one-pot approaches to syn-vinyl cyclopropyl alcoho

NIAID Data Ecosystem70

Diastereo- and Enantioselective Cyclopropanation with Chromium Fischer Carbene Complexes: Alkenyl Oxazolines as Useful Achiral and Chiral Substrates

手性环丙烷化

立体选择性反应

The cyclopropanation reaction of chromium Fischer carbene complexes with alkenyl oxazolines has been studied in both racemic and enantioselective fashions. The oxazolinyl group acts as both electron-a

NIAID Data Ecosystem60

Modular Enantioselective Synthesis of cis-Cyclopropanes through Self-Sensitized Stereoselective Photo-Decarboxylation with Benzothiazolines

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