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Symmetry Mismatching as a Tool in the Synthesis of Complex Supramolecular Solids with Multiple Cavities

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https://figshare.com/articles/dataset/Symmetry_Mismatching_as_a_Tool_in_the_Synthesis_of_Complex_Supramolecular_Solids_with_Multiple_Cavities/3348034
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Rotational symmetry of different parity of node and linker molecules has been used as a strategy in the synthesis of two architectural isomers with very different frameworks but identical cavities, both based on 1,3,5-tri(4-pyridyl)-2,4,6-triazine and C-methylcalix[4]resorcinarene. One of the two cavities in each of the solids has an unusual pentagonal shape.
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2016-05-07
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