Polyazolyl Chelate Chemistry. 12. An Unusual Mode of Coordination for the Hydrotris(methimazolyl)borato Ligand
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The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S‘ ‘-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)3}](Ru→B).
创建时间：
2016-05-07
