Asymmetric Total Synthesis of Cyclocitrinol
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_Cyclocitrinol/6106745
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资源简介：
The first and asymmetric
total synthesis of cyclocitrinol, an unusual
C25 steroid, has been accomplished in a linear sequence of 18 steps
from commercially available compound 11. The synthetically
challenging bicyclo[4.4.1] A/B ring system with a strained bridgehead
(anti-Bredt) double bond of cyclocitrinol was constructed efficiently
and diastereoselectively via a type II intramolecular [5 + 2] cycloaddition.
创建时间：
2018-04-06
