Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid
收藏Figshare2022-08-12 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Distinct_Reactivity_Modes_of_a_Copper_Hydride_Enabled_by_an_Intramolecular_Lewis_Acid/20483926
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资源简介：
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of chemical oxidation: hydride transfer to CO2 in the copper(I) state and oxidant-induced H2 evolution as well as alkyne reduction.
创建时间：
2022-08-12
