New Framework Iodoargentates: M(en)<sub>3</sub>Ag<sub>2</sub>I<sub>4</sub> (M = Zn, Ni) with Tridymite Topology
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Two novel framework compounds, Zn(en)3Ag2I4 (1) and Ni(en)3Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I42− with tridymite topolopy, and the discrete M(en)32+ cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.
创建时间：
2016-02-27
