Dynamic Chirality of (<i>E</i>)-5-Cyclononen-1-one and its Enolate
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It has been found that (E)-5-cyclononen-1-one (2a) exhibits marginal planar chirality owing to an insufficient topological constraint, whereas the enolates 3 derived from 2a show robust planar chirality. Enantioenriched enolates are easily prepared by enzymatic hydrolysis, and they show an ability to serve as chiral nucleophiles.
创建时间：
2011-02-16
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