[H<sub>2</sub>N{B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>}<sub>2</sub>]<sup>-</sup>: A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts
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The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2N{B(C6F5)3}2]-, the structure of which shows multiple intramolecular NH···F hydrogen bonding. Reaction with HCl affords [H(OEt2)2][H2N{B(C6F5)3}2], while treatment of zirconocene dimethyls with [CPh3][H2N{B(C6F5)3}2] gives highly active alkene polymerization catalysts.
创建时间：
2016-08-26
