Expanding Diversity without Protecting Groups: (+)-Sclareolide to Indolosesquiterpene Alkaloid Mycoleptodiscin A and Analogues
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https://figshare.com/articles/dataset/Expanding_Diversity_without_Protecting_Groups_Sclareolide_to_Indolosesquiterpene_Alkaloid_Mycoleptodiscin_A_and_Analogues/3380911
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资源简介：
Short and scalable
synthesis of the complex pentacyclic indolosesquiterpene
natural product mycoleptodiscin A has been achieved from commercially
available diterpenoid (+)-sclareolide in 19% overall yield. This approach
allows one to prepare various analogues of mycoleptodiscin using McMurry
cyclization as a key reaction with just three chromatographic purifications.
创建时间：
2016-05-27
