Total Synthesis of (±)-Grandilodine B
收藏Figshare2017-03-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_-Grandilodine_B/4753801
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The first total synthesis of the opened-type Kopsia alkaloid grandilodine B is reported. Four stereocenters of this alkaloid, three of them quaternary, are stereoselectively generated by a Diels–Alder reaction, a diastereoselective cyanation of tertiary alcohol, and a facial-selective nitrone 1,3-dipolar cycloaddition.
创建时间:
2017-03-15



