Development of a Series of P(CH<sub>2</sub>NCHR)<sub>3</sub> and Trisubstituted 1,3,5-Triaza-7-phosphaadamantane Ligands
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The synthesis and structure of a series of novel phosphine ligands derived from the condensation of P(CH2NH2) with aldehydes are described. Depending on the reaction conditions, either substituted tris(iminomethyl)phosphine, P(CH2NCHR)3, or 1,3,5-triaza-7-phosphaadamantane structures substituted at the “lower rim”, PTAR3, are obtained.
创建时间:
2016-06-03



