Hydrogen Uptake by an Inclined Polycatenated Dynamic Metal–Organic Framework Based Material
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https://figshare.com/articles/dataset/Hydrogen_Uptake_by_an_Inclined_Polycatenated_Dynamic_Metal_Organic_Framework_Based_Material/4499099
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资源简介:
A 2D + 2D → 3D inclined polycatenated
dynamic metal–organic
framework of {[Cu(4-bpe)(2-ntp)(H2O)2]·2H2O}n [1, where 2-ntp2– = 2-nitroterephthalate and 4-bpe = 1,2-bis-(4-pyridyl)ethane]
has been synthesized and characterized. The variable-temperature powder
X-ray diffraction study indicates the dynamic nature of the inclined
polycatenated framework, and the dehydrated framework with exposed
metal centers exhibits excellent type I H2 adsorption of
1.94 wt % at 77 K and 1 bar of pressure.
创建时间:
2016-12-28



