Aluminepin: Aluminum Analogues of Borepin and Gallepin
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https://figshare.com/articles/dataset/Aluminepin_Aluminum_Analogues_of_Borepin_and_Gallepin/2565082
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资源简介：
We report synthesis of dibenzoaluminepin as the first
aluminepin,
an aluminum analogue of borepin and gallepin. This compound contains
one molecule of ethereal solvent on the Al atom, which adopts a tetrahedral
geometry. The central 7-membered aluminepin ring has a boatlike conformation
and was characterized by single-crystal X-ray diffraction, 1H/13C NMR, and DFT studies. In addition, NICS, NBO, and
theoretical calculations provide insight into the nature of the bonding
and aromaticity of aluminepins.
创建时间：
2012-01-06
