A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media
收藏Figshare2016-05-02 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Self_Assembled_Molecular_Cage_for_Substrate_Selective_Epoxidation_Reactions_in_Aqueous_Media/3179278
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Encapsulation of a manganese porphyrin in a self-assembled molecular cage allows catalytic epoxidation of various substrates in 1:1 water/acetonitrile mixtures. The cage acts as a phase-transfer catalyst and creates a protective environment for the catalyst improving the stability. The encapsulated catalyst also allows discrimination between styrene derivatives of various sizes. In a direct competition experiment, the selectivity of the epoxidation reaction could be inverted with respect to a benchmark catalyst.
创建时间：
2016-05-02
