Synthesis, Structural Characterization, and Spectroscopy of the Cadmium−Cadmium Bonded Molecular Species Ar‘CdCdAr‘ (Ar‘ = C<sub>6</sub>H<sub>3</sub>-2,6-(C<sub>6</sub>H<sub>3</sub>-2,6-Pr<i><sup>i</sup></i><sup></sup><sub>2</sub>)<sub>2</sub>)
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The synthesis and first structural characterization of a cadmium−cadmium bonded molecular compound Ar‘CdCdAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) are reported. The existence of the Cd−Cd bond was established by 113Cd NMR spectroscopy and X-ray diffraction (Cd−Cd = 2.6257(5) Å). Like its group 12 analogue Ar‘ZnZnAr‘, DFT calculations showed that Ar‘CdCdAr‘ had significant p-character in the Cd−Cd σ-bonding HOMO.
创建时间：
2006-11-29
