Low-Valent Gallium, Indium, and Tin Compounds That Contain a Highly Fluorinated Tris(pyrazolyl)borate Ligand: Syntheses and Characterization of [HB(3,5-(CF<sub>3</sub>)<sub>2</sub>Pz)<sub>3</sub>]Ga, [HB(3,5-(CF<sub>3</sub>)<sub>2</sub>Pz)<sub>3</sub>]In, and [HB(3,5-(CF<sub>3</sub>)<sub>2</sub>Pz)<sub>3</sub>]Sn(CF<sub>3</sub>SO<sub>3</sub>)
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数据链接：
https://figshare.com/articles/dataset/Low-Valent_Gallium_Indium_and_Tin_Compounds_That_Contain_a_Highly_Fluorinated_Tris_pyrazolyl_borate_Ligand_Syntheses_and_Characterization_of_HB_3_5-_CF_sub_3_sub_sub_2_sub_Pz_sub_3_sub_Ga_HB_3_5-_CF_sub_3_sub_sub_2_sub_Pz_sub_3_sub_In_and_HB_3_5-_CF_sub_3/3626844数据链接链接失效反馈
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资源简介：
Syntheses and characterization of gallium(I), indium(I), and tin(II) complexes of the [HB(3,5-(CF3)2Pz)3]- ligand (where [HB(3,5-(CF3)2Pz)3]- = hydrotris(3,5-bis(trifluoromethyl)pyrazolyl)borate)) are reported. X-ray crystal structures of [HB(3,5-(CF3)2Pz)3]In and [HB(3,5-(CF3)2Pz)3]Sn(CF3SO3) show monomeric structures in the solid state. The In−N and Sn−N bond distances are longer than the corresponding bond distances of nonfluorinated analogues. NMR data of the gallium(I) adduct [HB(3,5-(CF3)2Pz)3]Ga are very similar to those of the indium(I) analogue suggesting similar solution structures.
创建时间：
2016-08-18
