Oxidative Addition of Thioesters to Iron(0): Active-Site Models for Hmd, Nature’s Third Hydrogenase
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https://figshare.com/articles/dataset/Oxidative_Addition_of_Thioesters_to_Iron_0_Active_Site_Models_for_Hmd_Nature_s_Third_Hydrogenase/2844343
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资源简介：
The thioester Ph2PC6H4-2-C(O)SPh reacts with Fe2(CO)9 to give [Ph2PC6H4C(O)]Fe(SPh)(CO)3, a model for the CO-inhibited active site of the enzyme Hmd. This species, which reversibly decarbonylates to give a diiron derivative, reacts with cyanide to give [[Ph2PC6H4C(O)]Fe(SPh)(CN)(CO)2]−.
创建时间：
2016-02-26
