Synthesis and Characterization of a 1,3-Phenylene-Bridged N‑Alkyl Bis(benzimidazole) CCC-NHC Pincer Ligand Precursor: Homobimetallic Silver and Rhodium Complexes and the Catalytic Hydrosilylation of Phenylacetylene
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_1_3_Phenylene_Bridged_N_Alkyl_Bis_benzimidazole_CCC_NHC_Pincer_Ligand_Precursor_Homobimetallic_Silver_and_Rhodium_Complexes_and_the_Catalytic_Hydrosilylation_of_Phenylacetylene/2452732
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资源简介：
A new CCC-NHC pincer ligand precursor architecture based
on 1,3-bis(N-alkylbenzimidazole)benzene
has been synthesized and metalated using Ag2O, forming
a homobimetallic Ag complex with a metal to ligand ratio of 1:1. The
Ag complex was treated with either [Rh(COD)Cl]2 or Rh(COD)2OTf and NBu4I to yield a homobimetallic Rh complex
by transmetalation. The Rh complexes were characterized, and an X-ray
structure is reported. Their catalytic activity in the hydrosilylation
of phenylacetylene is reported.
创建时间：
2016-04-05
