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Cation-Dependent Magnetic Ordering and Room-Temperature Bistability in Azido-Bridged Perovskite-Type Compounds

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https://figshare.com/articles/dataset/Cation_Dependent_Magnetic_Ordering_and_Room_Temperature_Bistability_in_Azido_Bridged_Perovskite_Type_Compounds/2362138
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A series of end-to-end azido-bridged perovskite-type compounds [(CH3)nNH4–n]­[Mn­(N3)3] (n = 1–4) were synthesized and characterized. Structural phase transitions indicating the general lattice flexibility were observed and confirmed by the crystal structures of different phases. These materials show cation-dependent magnetic ordering at up to 92 K and magnetic bistability near room temperature.
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2016-02-18
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