Insertion Reactions of Allenes Giving Vinyl Complexes
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https://figshare.com/articles/dataset/Insertion_Reactions_of_Allenes_Giving_Vinyl_Complexes/3264160
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资源简介：
Treatment of OsHCl(PPh3)3 with allenes
CH2CCHR at room temperature in benzene produced
the vinyl complexes OsCl(C(CH3)CHR)(CH2CCHR)(PPh3)2, instead of η3-allyl complexes as normally observed. DFT calculations show that the formation of the
vinyl complex is favored kinetically.
创建时间：
2005-10-10
