Insertion Reactions of Allenes Giving Vinyl Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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Treatment of OsHCl(PPh3)3 with allenes CH2CCHR at room temperature in benzene produced the vinyl complexes OsCl(C(CH3)CHR)(CH2CCHR)(PPh3)2, instead of η3-allyl complexes as normally observed. DFT calculations show that the formation of the vinyl complex is favored kinetically.
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2005-10-10
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