The Isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N‑Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/The_Isolation_of_Pd_OC_O_H_H_NHC_PR_sub_3_sub_NHC_N_Heterocyclic_Carbene_and_Its_Role_in_Alkene_and_Alkyne_Reductions_Using_Formic_Acid/2430616
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The [Pd(SIPr)(PCy3)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C–C multiple bonds using H2 formed in situ. The isolation of a key catalytic hydridoformatopalladium species, [Pd{OC(O)H}(H)(IPr)(PCy3)], is reported. The complex plays a key role in the Pd(0)-mediated formation of hydrogen from formic acid. Mechanistic and computational studies delineate the operational role of the palladium complex in this efficient tandem sequence.
创建时间：
2016-02-19
