Efficient and Selective Synthesis of (<i>E</i>)‑Enamides via Ru(II)-Catalyzed Hydroamidation of Internal Alkynes
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An efficient hydroamidation of benzylamides with internal alkynes catalyzed by Ru(II) has been developed. Various (E)-enamides were afforded in up to 95% yield for 28 examples. The protocol features excellent regio- and stereoselectivity, widely functional group tolerance, and easily accessible starting materials.
创建时间：
2016-02-12
