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Ditopic Double Pincer Palladacycle Catalyst for C−C Coupling

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Ditopic_Double_Pincer_Palladacycle_Catalyst_for_C_C_Coupling/3315823
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A ditopic palladacycle with SCS pincer coordination, L(PdCl)2 (1), was isolated and structurally characterized and represents the first example of a transition metal complex with a polythioamide-based macrocycle. Preliminary studies of 1 in the catalytic coupling of 4-iodotoluene and styrene indicated it to be robust in the presence of oxygen and high temperatures, with high turnover numbers in relatively short times.
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2016-05-06
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