A Mn<sub>17</sub> Octahedron with a Giant Ground-State Spin: Occurrence in Discrete Form and as Multidimensional Coordination Polymers
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
A [MnIII11MnII6(μ4-O)8(μ3-L)4]25+ (L = N3− or OCN−) octahedral unit is reported, occurring within 1D (1)∞ and 2D (2)∞ coordination polymers, as well as the corresponding 0D discrete cluster 3. It possesses a giant ground-state spin value, determined in the case of 3 to be S = 37, the second largest to be reported to date. In addition, compound 3 displays single-molecule magnet (SMM) behavior, and is thus the largest-spin SMM.
创建时间：
2016-02-26
